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MATERIAL SAFETY DATA SHEET

Data Revised: Jun.28.2002

Data Issued: Nov.1.2000

MSDS NO. F-31001

104

Personal Protective Equipment

Respiratory Protection :Not required under intended use.

Hand Protection :Not required under intended use.

Eye Protection :Not required under intended use.

Skin Protection :Not required under intended use.

Other Protective equipment :Use of a dust mask and goggles are recommended when

handling a large quantity of toner or during long term exposure,

as with any non-toxic dust.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Physical State : Solid Form: Powder Color: Black Odor: odorless

Ph :Not applicable

Boiling/Melting Point :Not applicable

Flash Point (°C ) :Not applicable

Explosion Properties :No data

Density (g/cm

) :5.4 (bulk density : 2.09)

Solubility in water :Negligible

10. STABILITY AND REACTIVITY

Stability :Stable

Hazardous Reactions :Dust explosion, like most finely divided organic powders.

Conditions to avoid :Electric discharge, throwing into fire.

Materials to avoid :Oxidizing Materials

Hazardous Decomposition Products :CO, CO

and NO

Further Information :None

11. TOXICOLOGICAL INFORMATION

Acute Toxicity

Ingestion (oral) :LD

>2000mg/kg (Rats) (Estimated from the constituent components)

Dermal :LD

>2000mg/kg (Rats)

Inhalation :No data

Eye irritation :Not an irritant (Rabbits)

Skin irritation :Not an irritant (Rabbits)

Skin sensitizer :No sensitization

Mutagenicity :Negative (Ames Test)

Carcinogenicity :In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen

(possible human carcinogen). This classification is given to chemicals for

which there is inadequate human evidence, but sufficient animal evidence

on which to base an opinion of carcinogenicity. The classification is based

upon the development of lung tumors in rats receiving chronic inhalation

exposures to free carbon black at levels that induce particle overload of the

lung. Studies performed in animal models other than rats did not show any

association between carbon black and lung tumors. Moreover, a two-year

cancer bioassay using a typical toner preparation containing carbon black

demonstrated no association between toner exposure and tumor

development in rats.

Chronic Effect :In a study in rats of chronic inhalation exposure to a typical toner, a mild to

moderate degree of lung fibrosis was observed in 92% of the rats in the high

concentration (16mg/m

) exposure group, and a minimal to mild degree of

fibrosis was noted in 22% of the animals in the middle (4mg/m

) exposure

group, but no pulmonary change was reported in the lowest (1mg/m

)

exposure group, the most relevant level to potential human exposures.

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