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MATERIAL SAFETY DATA SHEET

Page: 3/4

Date Revised: Jun. 28. 2002

Date Issued : Jun. 1. 1998

MSDS NO. F-00831

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Measures

Ventilation

Not required under intended use.

Exposure limit values

OSHA-PEL(USA)

15mg/m

(Total Dust) , 5mg/m

(Respirable Dust)

ACGIH-TLV(USA)

10mg/m

(Total Dust) , 3mg/m

(Respirable Dust)

Personal Protective Equipment

Respiratory Protection

Not required under intended use .

Hand Protection

Not required under intended use .

Eye Protection

Not required under intended use .

Skin Protection

Not required under intended use .

Other Protective equipment

Use of a dust mask and goggles are recommended when handling a large

quantity of toner or during long term exposure, as with any non-toxic dust.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Physical State

Solid Form

Powder Color

Black Odor

odorless

Ph :

Not applicable

Boiling/Melting Point :

Not applicable

Softening Point(°C ) :

No data

Flash Point(°C ) :

Not applicable

lgnition Point(°C ) :

No data

Explosion Properties :

No data

Density(g/cm³) :

1.1 (bulk density

0.34)

Solubility in water :

Negligible

10. STABILITY AND REACTIVITY

Stability :

Stable

Hazardous Reactions :

Dust explosion, like most finely divided organic powders.

Conditions to avoid :

Electric discharge, throwing into fire.

Materials to avoid :

Oxidizing Materials

Hazardous Decomposition Products :

CO, CO

and NO

Further Information :

None

11. TOXICOLOGICAL INFORMATION

Acute Toxicity

Ingestion(oral)

>2000mg/kg(Rats)

Dermal

>2000mg/kg(Rats)

Inhalation

No data

Eye irritation

Not an irritant

Skin irritation

Not an irritant

Skin sensitizer

No sensitization

Mutagenicity

Negative(Ames Test)

Carcinogenicity :

In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen (possible

human carcinogen). This classification is given to chemicals for which there is

inadequate human evidence, but sufficient animal evidence on which to base an

opinion of carcinogenicity. The classification is based upon the development of lung

tumors in rats receiving chronic inhalation exposures to free carbon black at levels that

induce particle overload of the lung. Studies performed in animal models other than

rats did not show any association between carbon black and lung tumors. Moreover, a

two-year cancer bioassay using a typical toner preparation containing carbon blac

demonstrated no association between toner exposure and tumor development in rats.

Chronic Effect :

In a study in rats of chronic inhalation exposure to a typical toner, a mild to moderate

degree of lung fibrosis was observed in 92% of the rats in the high concentration

(16mg/m

) exposure group, and a minimal to mild degree of fibrosis was noted in22%

of the animals in the middle (4mg/m

) exposure group, but no pulmonary change was

reported in the lowest (1mg/m

) exposure group, the most relevant level to potential

human exposures.

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