By making the prescr ibed number of strokes of the hand-held bellows, the
correct amount of air is drawn through the tube. This enables the tracer gas
evaluation to be made. The glass tube has graduation marks on it, and the
length of the discolouration caused by the reaction indicates the concentration
of tracer in the room air. Detector tubes can only be used once and must be
discarded after each sample taken.
This single shot method is not very accurate but it is cheap and easy to
operate. Therefore, it is suitable for a rough first estimate of the air change
rate. The interpretation of the result is performed using the integral decay
method (see Chapter 1, ‘Pulse injection’).
Characteristics of chemical indicator tubes:
.
Analysable tracers – CO
2
,H
2
O and many toxic gases that are not useable as
tracers.
.
Sensitivity – 0.01–0.3 per cent range for CO
2
.
.
Analysis time – one minute.
.
Accuracy – 5 per cent or 10 per cent of full scale.
Calibration of the analysers
Any analyser should be periodically calibrated by analysing standard samples,
which are mixtures of the tracers in air or other inert gas. The calibration
mixtures containing N
2
O and CO
2
must be moistened when a photo -acoustic
detector is used. To transfer the calibration mixture from the containers to
the analyser, never use valves or tubes that were previously used with pure
or high concentration tracers.
During the measurements, it is recommended to periodically sample and
analyse the outside air as a convenient zero refe rence, even if no tracer is
expected in the outdoor air.
Identification methods
Identification is to assess the values of some parameters in formulae from values of
variables involved in these formulae. There are several identification techniques.
Only some of them are presented below. The rationale of the presented methods
can be found in the literature, so only the final formulae are presented here.
Linear least square fit
The problem is the following: given N pairs of data (x; y), find the straight
line:
y ¼ a þ nx ð7:12Þ
fitting these points at the best. That means that the coefficients a and n should
be such that the sum of the ‘distances’ of the measured points to the line is a
minimum.
Common Methods and Techniques 147
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